DOE FE selects 17 projects to receive federal funding for R&D

These projects will advance FE’s efforts to: improve coal as a feedstock to produce value-added by-products; and to develop and test technologies that can use CO₂ – from coal-based power systems or other industrial sources – as the primary feedstock to reduce emissions and create valuable products. The coal feedstock projects will use existing pilot plants to produce an upgraded coal fuel and value-added by-products.

The National Energy Technology Laboratory (NETL) will manage the following projects:

Area of interest 1: lab-scale CO₂ conversion

CO₂ and Renewable Electricity into Chemicals: Formic Acid Production from Coal Flue Gas – Dioxide Materials (Boca Raton, FL) will develop an electrolyzer technology to enable formic acid to be economically manufactured from flue gas from a coal-fired pilot plant. This project will potentially lower the cost of CO₂ capture from coal-fired power plants; provide a feedstock for the bioprocessing industry that does not compete with the food supply; enable ethanol plants in the Midwest to meet the low carbon fuel standards; and enable economic production of a biodegradable polymer.

• DOE funding: US$800 000; non-DOE funding: US$200 000; total value: US$1 million.

Design of Transition-Metal/Zeolite Catalysts for Direct Conversion of Coal-Derived CO₂ to Aromatics – The Georgia Tech Research Corporation (Atlanta, GA) will develop a new catalytic process to produce valuable aromatic chemicals directly from CO₂ in coal-fired power plant flue gas. The new catalysts will enable a single reactor process for conversion of CO₂ to aromatics that can be deployed onsite at coal-fired power plants.

• DOE funding: US$800 000; non-DOE funding: US$231 376; total value: US$1 031 376.

Sustainable Conversion of Carbon Dioxide and Shale Gas to Green Acetic Acid via a Thermochemical Cyclic Redox Scheme – North Carolina State University (Raleigh, NC) will develop a comprehensive proof-of-concept for sustainable and cost-effective production of acetic acid, a critical building block for the plastic industry, from CO₂ and domestic shale gas. The project will remove the remaining challenges for the hybrid redox process technology, pushing it toward practical implementations for power plant flue gas.

• DOE funding: US$797 244; non-DOE funding: US$199 606; total value: US$996 850.

Novel Modular Electrocatalytic Processing for Simultaneous Conversion of Carbon Dioxide and Wet Shale Gas into Valuable Products – Ohio University (Athens, OH) aims to develop a process that uses solid oxide electrolysis to simultaneously convert CO₂ and ethane contained in wet natural gas into valuable products. This technology will provide fossil fuel-based power plants, oil and gas producers, and midstream gas processors a synergistic solution to carbon capture and ethane oversupply challenges.

• DOE funding: US$800 000; non-DOE funding: US$200 000; total value: US$1 million.

Electrochemical Conversion of Coal-Derived CO₂ into Fuels and Chemicals Using a Modified PEM Electrolyzer – Opus 12 (Berkeley, CA) will develop an electrochemical process to convert CO₂ into chemicals and fuels using only CO2, water, and electricity as inputs. A prototype has been developed that demonstrates high selectivity and current density for CO2 conversion to carbon monoxide that can be used to make high value products including methanol, acetic acid, polymers, and pharmaceuticals.

• DOE funding: US$800 000; non-DOE funding: US$200 000; total value: US$1 million.

Novel Process for CO₂ Conversion to Fuel – TDA Research (Wheat Ridge, CO) will develop a new sorbent-based process that can convert CO₂ captured from power plants, or other large sources, by reducing it with methane and water into a mixture of carbon monoxide and hydrogen, without generating additional CO₂ or greenhouse gas emissions. The process modeling and analysis will be used to demonstrate the techno-economic feasibility of the carbon-neutral process to convert CO2 into fuel.

• DOE funding: US$800 000; non-DOE funding: US$200 000; total value: US$1 million.

CO₂-to-Fuels through Novel Electrochemical Catalysis – Trustees of the Colorado School of Mines (Golden, CO) will demonstrate a modular and scalable reactor that economically upgrades CO₂ into fuels and chemicals. This project integrates carbon-carbon-coupling catalysts developed at the National Renewable Energy Laboratory with emerging proton-conducting ceramic membranes to directly produce synthetic fuels and high value chemicals from CO₂ feedstocks.

• DOE funding: US$800 000; non-DOE funding: US$206 467; total value: US$1 006 467.

Selective and Efficient Electrochemical Production of Neat Formic Acid from CO₂ Using Novel PGM-Free Catalysts – The University of Iowa (Iowa City, IA) will develop a lab-scale abiotic electrolyzer that cost-effectively converts CO₂ to formic acid. The project will design a process where CO₂ is collected from the flue gas of coal or fossil fuel combustion and fed to the electrolyzer. Supercritical CO₂ phase will be used for reduction, and a liquid water phase will be used for oxidation.

• DOE funding: US$733 668; non-DOE funding: US$199 933; total value: US$933 601.

An Intensified Electro-Catalytic Process for Production of Formic Acid from Power Plant CO₂ Emissions – The University of Kentucky (Lexington, KY) intends to develop and test an electro-catalytic method to produce formic acid from coal-derived CO₂ feedstocks as an alternative to production from methanol. This project will result in two major benefits: reducing the cost of capturing CO₂ from utility coal-fired units; and producing formic acid at a lower cost, potentially disrupting and advancing fuel cell, hydrogen storage, and chemical manufacturing markets.

• DOE funding: US$799 987; non-DOE funding: US$201 977; total value: US$1 001 964.

Synthetic Calcium Carbonate Production by CO₂ Mineralization of Industrial Waste Brines – The University of Wisconsin (Madison, WI) will develop two novel routes to produce precipitated calcium carbonate utilising reject streams – such as coal ashes and brines from oil and gas extraction or CO₂ storage operations – that are available in substantial quantities within the vicinity of coal power plants. The proposed process provides a unique route to integrate CO₂ emissions control and wastewater treatment for coal power plants, while producing a high value product to offset the economic burden associated with waste management.

• DOE funding: US$799 995; non-DOE funding: US$199 998; total value: US$999 993.

Unique Nanotechnology Converts Carbon Dioxide to Valuable Products – West Virginia University (Morgantown, WV) will develop a lab-scale, innovative nanotechnology that uses select amino acids to produce a commercial quality sodium bicarbonate directly from coal-fired power plant flue gas. The goal is to reduce CO₂ emissions while producing a commercially valuable product to offset carbon capture costs.

• DOE funding: US$800 000; non-DOE funding: US$218 205; total value: US$1 018 205.

Area of interest 2: field-scale CO₂ conversion

Novel Algae Technology to Utilize CO₂ for Value-Added Products – Helios-NRG (Amherst, NYrk) plans to develop an efficient process to convert CO₂ to value-added products comprising three key technologies: algae with high productivity and robust performance in the flue gas environment, energy-efficient algae dewatering, and production of nutraceuticals. Beneficiaries of this technology include coal- and natural gas-fuelled power plants; large industrial emitters of CO₂; and entities involved in algae-to-biofuels, food and nutraceuticals.

• DOE funding: US$1 499 558; non-DOE funding: US$375 082; total value: US$1 874 640.

Beneficial Use of CO₂ from Coal-Fired Power Plants for Production of Animal Feeds – MicroBio Engineering (San Luis Obispo, CA) intends to develop a process to produce microalgal biomass for the conversion of CO₂ from coal-fired power plant flue gas into animal feeds, to demonstrate the potential of power plant CO₂ utilisation for generating products with large markets. The primary product will be air-dried algal biomass with value as a premium animal feed, based on the omega-3 oils, carotenoids and protein content.

• DOE funding: US$1 442 854; non-DOE funding: US$368 155; total value: US$1 811 009.

Field-Scale Testing of the Thermocatalytic Ethylene Production Process Using Ethane and Actual Coal-Fired Flue Gas CO₂ – The Southern Research Institute (Birmingham, AL) aims to demonstrate a nano-engineered, catalyst-driven thermochemical process at field scale that produces a high yield of ethylene using CO₂ derived from coal-fired flue gas and ethane. The project’s long-term goal is a commercially viable and environmentally friendly technology for producing light olefins via CO₂ utilisation.

• DOE funding: US$1 499 442; non-DOE funding: US$375 458; total value: US$1 874 900.

A Scalable Process for Upcycling Carbon Dioxide and Coal Combustion Residues into Construction Products – The University of California, Los Angeles (Los Angeles, CA) plans to accelerate the development of a CO₂ mineralisation process that uses CO2 in flue gas and coal combustion residues to synthesise CO2NCRETE, a functional replacement for traditional concrete. The process will offer the coal power sector a pioneering pathway for solid waste and CO₂ utilisation to produce a value-added product with a large addressable market.

• DOE funding: US$1.5 million; non-DOE funding: US$382 265; total value: US$1 882 265.

Area of interest 3: coal beneficiation pilot plant testing

The Novel Charfuel® Coal Refining Process 18 TPD Pilot Plant Project for Co-Producing an Upgraded Coal Product and Commercially Valuable Co-Products – CarbonFuels LLC (Denver, CO) aims to employ the novel Charfuel Coal Refining Process at its existing, permitted pilot plant to produce an upgraded coal product and a number of organic and inorganic coproducts in order to produce engineering and product data that will then be used to design a commercial-scale integrated facility.

• DOE funding: US$2 million; non-DOE funding: US$1 180 519; total value: US$3 180 519.

Pilot-Scale Testing of the Hydrophobic-Hydrophilic Separation Process to Produce Value-Added Products from Waste Coal – The Minerals Refining Company (Richmond, VA) plans to demonstrate the technical, economic, and environmental benefits of the hydrophobic-hydrophilic separation process for producing high purity, value-added clean coal and specialty carbon products from discarded coal wastes. The project will provide thorough analyses to identify pathways for promoting commercial acceptance.

• DOE funding: US$2 million; non-DOE funding: US$500 000; total value: US$2.5 million.

Read the article online at: https://www.worldcoal.com/coal/02112018/doe-fe-selects-17-projects-to-receive-federal-funding-for-rd/